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慶應義塾大学 理工学部 化学科 垣内研究室 有機金属化学研究室 |
住所 〒223-8522 神奈川県横浜市港北区日吉3-14-1
慶應義塾大学理工学部 矢上キャンパス22棟5階(地図) 電話 045-566-1591 |
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4) Selective Monoarylation of Aromatic Ketones via C–H Bond Cleavage by Trialkylphosphine Ruthenium Catalysts I. Suzuki, H. Kondo, T. Kochi, F. Kakiuchi J. Org. Chem., 84(20), 12975-12982 (2019). doi 3) Iron‐Catalyzed ortho-selective C–H Alkylation of Aromatic Ketones with N-Alkenylindoles and Partial Indolylation via 1,4-Iron Migration N. Kimura, T. Kochi, F. Kakiuchi Asian J. Org. Chem., 8(7), 1115-1117 (2019). doi 2) Synthesis of N-Arylpyrazoles by Palladium-Catalyzed Coupling of Aryl Triflates with Pyrazole Derivatives S. Onodera, T. Kochi, F. Kakiuchi J. Org. Chem., 84(10), 6508-6515 (2019). doi 1) Metal-Catalyzed Sequential Formation of Distant Bonds in Organic Molecules: Palladium-Catalyzed Hydrosilylation/Cyclization of 1,n-Dienes via Chain Walking T. Kochi, K. Ichinose, M. Shigekane, T. Hamasaki, F. Kakiuchi Angew. Chem. Int. Ed., 58(16), 5261-5265 (2019). doi 【2018年】 3) Selective Long-Distance Isomerization of Terminal Alkenes via Nondissociative Chain Walking Y. Yamasaki, T. Kumagai, S. Kanno, F. Kakiuchi, T. Kochi J. Org. Chem., 83(16), 9322-9333 (2018). doi 2) Direct Alkenylation of Allylbenzenes via Chelation-Assisted C-C Bond Cleavage S. Onodera, S. Ishikawa, T. Kochi, F. Kakiuchi, J. Am. Chem. Soc., 140(31), 9788-9792 (2018). doi (This article was selected as a "Supplementary Cover Art".) doi 1) Palladium‐Catalyzed C‐H Iodination of N‐(8‐Quinolinyl)benzamide Derivatives Under Electrochemical and Non‐Electrochemical Conditions K. Sano, N. Kimura, T. Kochi, F. Kakiuchi, Asian J. Org. Chem., 7(7), 1311-1314 (2018). doi (This article was selected as a "Front Cover".) doi 【2017年】 8) Iron-Catalyzed Regioselective Anti-Markovnikov Addition of C-H Bonds in Aromatic Ketones to Alkenes N. Kimura, T. Kochi, F. Kakiuchi, J. Am. Chem. Soc., 139(42), 14849-14852 (2017). doi (This article was selected as the most read article Top 20 on a monthly basis.) 7) Synthesis of Fluorine-Containing Tetraarylanthracenes via Ruthenium-Catalyzed C-O or C-F Arylation and Their Crystal Structures A. Izumoto, H. Kondo, T. Kochi, F. Kakiuchi, Synlett, 28(19), 2609-2613 (2017). doi 6) Formation of α-Monosubstituted Propargylamines from Terminal Alkynes and Secondary Amines Using a (PNO)Rh/Cu Tandem Catalyst System S. Takano, T. Kochi, F. Kakiuchi, Chem. Lett., 46(11), 1620-1623 (2017). doi (This article was selected as Editor's Choice.) Open Access 5) Palladium-Catalyzed Ortho-Selective C-H Chlorination of Benzamide Derivatives under Anodic Oxidation Conditions M. Konishi, K. Tsuchida, K. Sano, T. Kochi, F. Kakiuchi, J. Org. Chem., 82(16), 8716-8724 (2017). doi 4) Synthesis of Dibenzo[h,rst]pentaphenes and Dibenzo[fg,qr]pentacenes by the Chemoselective C-O Arylation of Dimethoxyanthraquinones Y. Suzuki, K. Yamada, K. Watanabe, T. Kochi, Y. Ie, Y. Aso, F. Kakiuchi, Org. Lett., 19(14), 3791-3794 (2017). doi 3) Selective Monoarylation of Aromatic Ketones and Esters via Cleavage of Aromatic Carbon-Heteroatom Bonds by Trialkylphosphine Ruthenium Catalysts H. Kondo, T. Kochi, F. Kakiuchi, Org. Lett., 19(4), 794-797 (2017). doi 2) Ruthenium-Catalyzed Ortho C-H Arylation of Aromatic Nitriles with Arylboronates and Observation of Partial Para Arylation Y. Koseki, K. Kitazawa, M. Miyake, T. Kochi, F. Kakiuchi, J. Org. Chem., 82(13), 6503-6510 (2017). doi (This article was selected as featured article.) doi 1) Syntheses of RuHCl(CO)(PAr3)3 and RuH2(CO)(PAr3)3 Containig Various Triarylphosphines and Their Use for Arylation of Sterically Congested Aromatic C-H Bonds Y. Ogiwara, M. Miyake, T. Kochi, F. Kakiuchi, Organometallics, 36(1), 159-164 (2017). doi 【2016年】 2) Synthesis and Reactivity of Phosphine-Quinolinolato Rhodium Complexes: Intermediacy of Vinylidene and (Amino)carbene Complexes in the Catalytic Hydroamination of Terminal Alkynes S. Takano, T. Kochi, F. Kakiuchi, Organometallics, 35(24), 4112-4125 (2016). doi 1) Chain-Walking Cycloisomerization of 1,n-Dienes Catalyzed by Pyridine-Oxazoline Palladium Catalysts and Its Application to Asymmetric Synthesis T. Hamasaki, F. Kakiuchi, T. Kochi, Chem. Lett., 45(3), 297-299 (2016). doi 【2015年】 3) Chain Walking as a Strategy for Carbon-Carbon Bond Formation at Unreactive Sites in Organic Synthesis: Catalytic Cycloisomerization of Various 1,n-Dienes T. Hamasaki, Y. Aoyama, J. Kawasaki, F. Kakiuchi, T. Kochi J. Am. Chem. Soc., 137(51), 16163-16171 (2015). doi 2) Catalytic Formation of α-Aryl Ketones by C-H Functionalization with Cyclic Alkenyl Carbonates and One-Pot Synthesis of Isocoumarins Y. Hara, S. Onodera, T. Kochi, F. Kakiuchi, Org. Lett., 17(19), 4850-4853 (2015). doi 1) Ruthenium-Catalyzed Monoalkenylation of Aromatic Ketones by Cleavage of Carbon-Heteroatom Bonds with Unconventional Chemoselectivity H. Kondo, N. Akiba, T. Kochi, F. Kakiuchi, Angew. Chem. Int. Ed., 54(32), 9293-9297 (2015). doi 【2014年】 3) Palladium-Catalyzed Regioselective Homocoupling of Arenes Using Anodic Oxidation: Formal Electrolysis of Aromatic Carbon-Hydrogen Bonds F. Saito, H. Aiso, T. Kochi, F. Kakiuchi, Organometallics, 33(22), 6704-6707 (2014). doi 2) Ruthenium-catalyzed Ortho-selective Aromatic C-H Alkenylation with Alkenyl Carbonates Y. Ogiwara, T. Kochi, F. Kakiuchi, Chem. Lett., 43(5), 667-669 (2014). doi 1) Ruthenium-Catalyzed Ortho-Selective C-H Alkenylation of Aromatic Compounds with Alkenyl Esters and Ethers Y. Ogiwara, M. Tamura, T. Kochi, Y. Matsuura, N. Chatani, F. Kakiuchi, Organometallics, 33(1), 402-420 (2014). doi 【2013年】 5) Copper-Catalyzed Electrochemical Chlorination of 1,3-Dicarbonyl Compounds Using Hydrochloric Acid K. Tsuchida, T. Kochi, F. Kakiuchi, Asian J. Org. Chem., 2(11), 935-937 (2013). doi 4) Ruthenium-Catalyzed Reductive Deamination and Tandem Alkylation of Aniline Derivatives T. Koreeda, T. Kochi, F. Kakiuchi, J. Organomet. Chem., 741-742, 148-152 (2013). doi 3) Rhodium-Catalyzed Dimerization of Arylacetylenes and Addition of Malonates to 1,3-Enynes K. Mochizuki, K. Sakai, T. Kochi, F. Kakiuchi, Synthesis, 45(15)，2088-2092（2013）. doi 2) Rhodium-Catalyzed Intermolecular [2+2] Cycloaddition of Terminal Alkynes with Electron-Deficient Alkenes K. Sakai, T. Kochi, F. Kakiuchi, Org. Lett., 15(5), 1024-1027 (2013). doi (This article was selected as the most read article Top 20 on a monthly basis.) 1) Substituent Effects on Stoichiometric and Catalytic Cleavage of Carbon-Nitrogen Bonds in Aniline Derivatives by Ruthenium-Phosphine Complexes T. Koreeda, T. Kochi, F. Kakiuchi, Organometallics, 32(2), 682-690 (2013). doi 【2012年】 3) Chain-Walking Strategy for Organic Synthesis: Catalytic Cycloisomerization of 1,n-Dienes T. Kochi, T. Hamasaki, Y. Aoyama, J. Kawasaki, F. Kakiuchi, J. Am. Chem. Soc., 134(40), 16544-16547 (2012). doi 2) Catalytic Electrochemical C-H Iodination and One-Pot Arylation by ON/OFF Switching of Electric Current H. Aiso, T. Kochi, H. Mutsutani, T. Tanabe, S. Nishiyama, F. Kakiuchi, J. Org. Chem., 77(17), 7718-7724 (2012). doi 1) Short Synthesis of Alkyl-Substituted Acenes Using Carbonyl-Directed C-H and C-O Functionalization D. Matsumura, K. Kitazawa, S. Terai, T. Kochi, Y. Ie, M. Nitani, Y. Aso, F. Kakiuchi, Org. Lett., 14(15), 3882-3885 (2012). doi 【2011年】 6) Ruthenium-Catalyzed Arylation of Fluorinated Aromatic Ketones via Ortho-Selective Carbon-Fluorine Bond Cleavage K. Kawamoto, T. Kochi, M. Sato, E. Mizushima, F. Kakiuchi, Tetrahedron Lett., 52, 5888-5890 (2011). doi 5) Ruthenium-Catalyzed Acylation of Arylpyridines with Acyl Chlorides via ortho-Selective C-H Bond Cleavage T. Kochi, A. Tazawa, K. Honda, F. Kakiuchi, Chem. Lett., 40, 1018-1020 (2011). doi 4) Rhodium-Catalyzed anti-Markovnikov Addition of Secondary Amines to Arylacetylenes at Room Temperature K. Sakai, T. Kochi, F. Kakiuchi, Org. Lett., 13(15), 3928-3931 (2011). doi 3) Ruthenium-Catalyzed Conversion of sp3 C-O Bonds in Ethers to C-C Bonds Using Triarylboroxines Y. Ogiwara, T. Kochi, F. Kakiuchi, Org. Lett., 13(12), 3254-3257 (2011). doi 2) Convenient Synthesis of Dibenzo[a,h]anthracenes and Picenes via C-H Arylation of Acetophenones with Arenediboronates K. Kitazawa, T. Kochi, M. Nitani, Y. Ie, Y. Aso, F. Kakiuchi, Chem. Lett., 40, 300-302 (2011). doi 1) Rhodium-Catalyzed anti-Markovnikov Intermolecular Hydroalkoxylation of Terminal Acetylenes M. Kondo, T. Kochi, F. Kakiuchi, J. Am. Chem. Soc., 133(1), 32-34 (2011). doi 【2010年】 5) Room-Temperature Regioselective C-H/Olefin Coupling of Aromatic Ketones Using an Activated Ruthenium Catalyst with a Carbonyl Ligand and Structural Elucidation of Key Intermediates F. Kakiuchi, T. Kochi, E. Mizushima, S. Murai, J. Am. Chem. Soc., 132(50), 17741-17750 (2010). doi 4) Control of Product Selectivity by a Styrene Additive in Ruthenium-Catalyzed C-H Arylation S. Hiroshima, D. Matsumura, T. Kochi, F. Kakiuchi, Org. Lett., 12(22), 5318-5321 (2010). doi 3) Solution-phase Assembly of a Rhodium Complex via Specific Hydrogen Bonding between Barbituric Acid and Triaminopyrimidine Moieties M. Kondo, T. Kochi, M. Sato, A. Kitajima, F. Kakiuchi, Chem. Lett., 39, 1166-1167 (2010). doi 2) Ruthenium-Catalyzed Arylation of Ortho C-H Bond in an Aromatic with an Arylboronate: 8-Phenyl-1-Tetralone K. Kitazawa, T. Kochi, F. Kakiuchi, Org. Synth., 87, 209 (2010). 1) RuH2(CO)(PPh3)3-Catalyzed Arylation of Aromatic Esters Using Arylboronates via C-H Bond Cleavages K. Kitazawa, M. Kotani, T. Kochi, M. Langeloth, F. Kakiuchi, J. Organomet. Chem., 695, 1163-1167 (2010). doi 【2009年】 5) Palladium-Catalyzed Aromatic C-H Halogenation with Hydrogen Halides by Means of Electrochemical Oxidation F. Kakiuchi, T. Kochi, H. Mutsutani, N. Kobayashi, S. Urano, M. Sato, S. Nishiyama, T. Tanabe, J. Am. Chem. Soc., 131(32), 11310-11311 (2009). doi 4) Cleavage of C-N Bonds in Aniline Derivatives on a Ruthenium Center and Its Relevance to Catalytic C-C Bond Formation T. Koreeda, T. Kochi, F. Kakiuchi, J. Am. Chem. Soc., 131(21), 7238-7239 (2009). doi 3) Convenient Synthesis of Tetra- and Hexaarylanthracenes by Means of RuH2(CO)(PPh3)3-Catalyzed C-H Arylation of Anthraquinone with Arylboronates K. Kitazawa, T. Kochi, M. Sato, F. Kakiuchi, Org. Lett., 11(9), 1951-1954 (2009). doi 2) Ruthenium-Catalyzed Amino- and Alkoxycarbonylations with Carbamoyl Chlorides and Alkyl Chloroformates via Aromatic C-H Bond Cleavage T. Kochi, S. Urano, H. Seki, E. Mizushima, M. Sato, F. Kakiuchi, J. Am. Chem. Soc., 131(8), 2792-2793 (2009). doi 1) Unique Effect of Coordination of an Alkene Moiety in Products on Ruthenium-Catalyzed Chemoselective C-H Alkenylation S. Ueno, T. Kochi, N. Chatani, F. Kakiuchi, Org. Lett., 11(4), 855-858 (2009). doi 【2007年】 4) The Ru(cod)(cot)-Catalyzed Alkenylation of Aromatic C-H Bonds with Alkenyl Acetates Y. Matsuura, M. Tamura, T. Kochi, M. Sato, N. Chatani, and F. Kakiuchi, J. Am. Chem. Soc., 129, 9858-9859 (2007). doi 3) Ruthenium-Catalyzed Carbon-Carbon Bond Formation via the Cleavage of an Unreactive Aryl Carbon-Nitrogen Bond in Aniline Derivatives with Organoboronates S. Ueno, N. Chatani, and F. Kakiuchi, J. Am. Chem. Soc., 129, 6098-6099 (2007). doi 2) Regioselective Alkenylation of Aromatic Ketones with Alkenylboronates Using a RuH2(CO)(PPh3)3-Catalyst via Carbon-Hydrogen Bond Cleavage S. Ueno, N. Chatani, and F. Kakiuchi, J. Org. Chem., 72, 3600-3602 (2007). doi 1) Ru/C-Catalyzed Carbonylation at ortho-C-H Bonds in 2-Phenylpyridines S. Imoto, T. Uemura, F. Kakiuchi, and N. Chatani, Synlett, 170-172 (2007). 【2006年】 2) Observation of the Oxidative Addition of the Aryl Carbon-Oxygen Bond to a Ruthenium Complex and Consideration of the Relative Reactivity between Aryl Carbon-Oxygen and Aryl Carbon-Hydrogen Bonds S. Ueno, E. Mizushima, N. Chatani, and F. Kakiuchi, J. Am. Chem. Soc., 128(51), 16516-16517 (2006). doi 1) Synthesis of Ru(CO)2(PPh3)(SP)] and [Ru(CO)(PPh3)2(SP)] and Their Catalytic Activities for the Hydroamination of Phenylacetylene E. Mizushima, N. Chatani, F. Kakiuchi, J. Organomet. Chem., 691, 5739-5745 (2006). doi 【2005年】 2) Rhodium-Catalyzed C-H－CO－Olefin Coupling Reactions - A Chelation-Assisted Direct Carbonylation at the ortho C-H Bond in the Benzene Ring of 2-Arylpyridines N. Chatani, T. Uemura, T. Asaumi, Y. Ie, F. Kakiuchi, and S. Murai, Can. J. Chem., 83, 755(2005). 1) A RuH2(CO)(PPh3)3-Catalyzed Regioselective Arylation of Aromatic Ketones with Arylboronates via Carbon-Hydrogen Bond Cleavage F. Kakiuchi, Y. Matsuura, S. Kan, and N. Chatani, J. Am. Chem. Soc., 127, 5936 (2005). doi 【2004年】 5) Ru3(CO)12-Catalyzed Silylation of Benzylic C-H Bonds in Arylpyridines and Arylpyrazoles with Hydrosilanes via C-H Bond Cleavage F. Kakiuchi, K. Tsuchiya, M. Matsumoto, E. Mizushima, and N. Chatani, J. Am. Chem. Soc., 126, 12792 (2004). 4) A New Ketone Synthesis by Palladium-Catalyzed Cross-Coupling Reactions of Esters with Organoboron Comounds H. Tatamidani, F. Kakiuchi, and N. Chatani, Org. Lett., 6, 3597 (2004). 3) Catalytic Cross-Coupling Reaction of Esters with Organoboron Compounds and Decarbonylative Reduction of Esters with HCOONH4: A New Route to Acyl Transition Metal Complexes through the Cleavage of Acyl-Oxygen Bonds in Esters H. Tatamidani, K. Yokota, F. Kakiuchi, and N. Chatani, J. Org. Chem., 69, 5615 (2004). 2) Ruthenium- and Rhodium-Catalyzed Direct Carbonylation of the Ortho C-H Bond in the Benzene Ring of N-Arylpyrazoles T. Asaumi, T. Matsuo, T. Fukuyama, Y. Ie, F. Kakiuchi, and N. Chatani, J. Org. Chem., 69, 4433 (2004). 1) The Ruthenium-Catalyzed Functionalization of Aryl Carbon-Oxygen Bonds in Aromatic Ethers with Organoboron Compound F. Kakiuchi, M. Usui, S. Ueno, N. Chatani, and S. Murai, J. Am. Chem. Soc., 126, 2706 (2004). 【2003年】 3) Ruthenium-Catalyzed C-H/CO/Olefin Coupling Reaction of N-Arylpyrazoles. Extraordinary Reactivity of N-Arylpyrazoles toward Carbonylation at C-H Bonds T. Asaumi, N. Chatani, T. Matsuo, F. Kakiuchi, and S. Murai, J. Org. Chem., 68, 7538 (2003). 2) The Ruthenium-Catalyzed Silylation of Aromatic C-H Bonds with Triethylsilane F. Kakiuchi, M. Matsumoto, K. Tsuchiya, K. Igi, T. Hayamizu, N. Chatani, and S. Murai, J. Organomet. Chem., 686, 134 (2003). (Special Issue) 1) A Ruthenium-Catalyzed Reaction of Aromatic Ketones with Arylboronates: A New Method for the Arylation of Aromatic Compounds via C-H bond Cleavage F. Kakiuchi, S. Kan, K. Igi, N. Chatani, and S. Murai, J. Am. Chem. Soc., 125, 1698 (2003). 【2002年】 3) Ru3(CO)12-Catalyzed C-H/CO/Olefin Coupling of N-Pyridylindolines. Direct Carbonylation at a C-H Bond δ to the Pyridine Nitrogen. N. Chatani, S. Yorimitsu, T. Asaumi, F. Kakiuchi, and S. Murai, J. Org. Chem., 67, 7557 (2002). 2) A New Chelation-assistance Mode for a Ruthenium-Catalyzed Silylation at the C-H Bond in Aromatic Ring with Hydrosilanes F. Kakiuchi, K. Igi, M. Matsumoto, T. Hayamizu, N. Chatani, and S. Murai, Chem. Lett., 396 (2002). 1) Ruthenium-Catalyzed Addition of Olefinic C-H Bonds in Conjugate Enones to Acetylenes to Give Conjugate Dienones F. Kakiuchi, T. Uetsuhara, Y. Tanaka, N. Chatani, and S. Murai, J. Mol. Catal. A, 182-183, 511 (2002). 【2001年】 6) Ru3(CO)12-Catalyzed Coupling Reaction of sp3 C-H Bonds adjacent to a Nitrogen Atom in Alkylamines with Alkenes N. Chatani, T. Asaumi, S. Yorimitsu, T. Ikeda, F. Kakiuchi, and S. Murai, J. Am. Chem. Soc., 123, 10935 (2001). 5) Mechanistic Study of the Ru(H)2(CO)(PPh3)3-Catalyzed Addition of C-H Bonds in Aromatic Esters to Olefins F. Kakiuchi, H. Ohtaki, M. Sonoda, N. Chatani, and S. Murai, Chem. Lett., 918 (2001). 4) The Ruthenium-Catalyzed Reductive Decarbonyllation of Esters: Catalytic Reactions Involving the Cleavage of Acyl-oxygen Bonds of Esters N. Chatani, H. Tatamidani, Y. Ie, F. Kakiuchi, and S. Murai, J. Am. Chem. Soc., 123, 4849 (2001). 3) Ruthenium-Catalyzed Dehydrogenative Silylation of Aryloxazolines with Hydrosilanes via C-H Bond Cleavage F. Kakiuchi, K. Igi, M. Matsumoto, N. Chatani, and S. Murai, Chem. Lett., 422 (2001). 2) The Transition Metal-Catalyzed Addition of C-H Bonds in Aromatic Hydrazones to Olefins F. Kakiuchi, T. Tsujimoto, M. Sonoda, N. Chatani, and S. Murai, Synlett, 948 (2001). 1) The Ruthenium-Catalyzed Addition of β C-H Bonds in Aldehydes to Olefins F. Kakiuchi, T. Sato, K. Igi, N. Chatani, and S. Murai, Chem. Lett., 386 (2001). 【2000年】 6)Carbonylation at sp3 C-H Bonds Adjacent to a Nitrogen Atom in Alkylamines Catalyzed by Rhodium Complexes N. Chatani, T. Asaumi, T. Ikeda, S. Yorimitsu, Y. Ishii, F. Kakiuchi, and S. Murai, J. Am. Chem. Soc., 122, 12882 (2000). 5)Atropselective Alkylation of Biaryl Compounds by Means of Transition Metal-Catalyzed C-H/olefin Coupling F. Kakiuchi, P. Le Gendre, A. Yamada, H. Ohtaki, and S. Murai, Tetrahedron: Asymmetry, 11, 2647 (2000). 4) Acylation of Five-Membered N-Heteroaromatic Compounds by Ruthenium Carbonyl-catalyzed Direct Carbonylation at a C-H Bond N. Chatani, T. Fukuyama, H. Tatamidani, F. Kakiuchi, and S. Murai, J. Org. Chem., 65, 4039 (2000). 3) A New Synthetic Route to Heteroarylsilanes via Ruthenium-Catalyzed C-H/SiR3Coupling F. Kakiuchi, M. Matsumoto, M. Sonoda, T. Fukuyama, N. Chatani, S. Murai, N. Furukawa, and Y. Seki, Chem. Lett., 750 (2000). 2) Direct Carbonylation at a C-H Bond in the Benzene Ring of 2-Phenyloxazolines Catalyzed by Ru3(CO)12. Scope, Limitations, and Mechanistic Aspects Y. Ie, N. Chatani, T. Ogo, D. R. Marshall, T. Fukuyama, F. Kakiuchi, and S. Murai, J. Org. Chem., 65, 1475 (2000). 1) The Co2(CO)8-Catalyzed Hydrosilylation of Oxygen-containing Olefins: Silylmetalation as a Key Step N. Chatani, T. Kodama, Y. Kajikawa, H. Murakami, F. Kakiuchi, S.-I. Ikeda, and S. Murai, Chem. Lett., 14 (2000). 【1999年】 5) The Ruthenium-Catalyzed Addition of C-H Bonds in Aromatic Nitriles to Olefins F. Kakiuchi, M. Sonoda, T. Tsujimoto, N. Chatani, and S. Murai, Chem. Lett., 1083 (1999). 4) Ru3(CO)12-Catalyzed Decarbonylative Cleavage of a C-C Bond of Alkyl Phenyl Ketones N. Chatani, Y. Ie, F. Kakiuchi, and S. Murai, J. Am. Chem. Soc., 121, 8645 (1999). 3) Transition Metal-Catalyzed Dehydrogenative Germylation of Olefins with Tri-n-Butylgermane N. Furukawa, N. Kourogi, Y. Seki, F. Kakiuchi, and S. Murai, Organometallics, 18, 3764 (1999). 2) Ruthenium-Catalyzed Coupling of Aromatic Carbon-hydrogen Bonds in Aromatic Imidates with Olefins F. Kakiuchi, T. Sato, M. Yamauchi, N. Chatani, and S. Murai, Chem. Lett., 19 (1999). 1) Silyl Group Transfer from Allylsilanes to Olefins Catalyzed by a Ruthenium(II) Complex F. Kakiuchi, A. Yamada, N. Chatani, S. Murai, N. Furukawa, and Y. Seki, Organometallics, 18, 2033 (1999). 【1998年】 5) Ru3(CO)12-Catalyzed Site-Selective Carbonylation Reactions at a C-H Bond in Aza-heterocycles T. Fukuyama, N. Chatani, J. Tatsumi, F. Kakiuchi, and S. Murai, J. Am. Chem. Soc., 120, 11522 (1998). 4) New Protocol for the Siteselective Alkylation and Vinylation of Aromatic Compounds. Catalyst-Specific Reactions F. Kakiuchi, T. Sato, T. Tsujimoto, M. Yamauchi, N. Chatani, and S. Murai, Chem. Lett., 1053 (1998). 3) Ruthenium-Catalyzed Reactions of Acyclic α,β-Enones with Olefins and Their Reaction Mechanisms T. Sato, F. Kakiuchi, N. Chatani, and S. Murai, Chem. Lett., 893 (1998). 2) Ru3(CO)12- and Rh4(CO)12-Catalyzed Reactions of Pyridyl Olefins or N-(2-Pyridyl)enamines with CO and olefins. Carbonylation at Olefinic C-H Bonds N. Chatani, Y. Ishii, Y. Ie, F. Kakiuchi, and S. Murai, J. Org. Chem., 63, 5129 (1998). 1) Transition Metal-Catalyzed Intramolecular Cyclization of 1,5- and 1,6-Dienes via Direct Cleavage and Addition of the Carbon-hydrogen Bond. N. Fujii, F. Kakiuchi, A. Yamada, N. Chatani, and S. Murai, Bull. Chem. Soc. Jpn., 71, 285 (1998). 【1997年】 9) Ruthenium-Catalyzed Addition of Carbon-Hydrogen Bonds in Aromatic Ketones to Olefins. The Effect of Various Substituents at the Aromatic Ring M. Sonoda, F. Kakiuchi, N. Chatani, and S. Murai, Bull. Chem. Soc. Jpn., 70, 3117 (1997). 8) Rhodium-Catalyzed Reaction of N-Acylpiperazines with CO and ethylene. Carbonylation at a C-H Bond Directed by an Amido Group Y. Ishii, N. Chatani, F. Kakiuchi, and S. Murai, Tetrahedron Lett., 38, 7565 (1997). 7) Asymmetric Catalysis with Water: Efficient Kinetic Resolution of Terminal Epoxides by means of Catalytic Hydrolysis M. Tokunaga, J. F. Larrow, F. Kakiuchi, and E. N. Jacobsen, Science, 277, 936 (1997). 6) Rhodium-Catalyzed Reaction of N-(2-Pyridinyl)piperazines with CO and Ethylene. A Novel Carbonylation at a C-H Bond in the Piperazine Ring Y. Ishii, N. Chatani, F. Kakiuchi, and S. Murai, Organometallics, 16, 3615 (1997). 5) A New Synthetic Method for the Preparation of Indenones from Aromatic Imines. Ru3(CO)12-Catalyzed Carbonylation at an ortho C-H Bond in the Aromatic Imines T. Fukuyama, N. Chatani, F. Kakiuchi, and S. Murai, J. Org. Chem., 62, 5647 (1997) 4) Aysmmetric Intramolecular C-H/Olefin Coupling: Asymmetric Cyclization Reactions of 1,5-Dienes Catalyzed by Rhodium Complexes N. Fujii, F. Kakiuchi, A. Yamada, N. Chatani, and S. Murai, Chem. Lett., 425 (1997). 3) Catalytic Dimerization of Acrylonitrile K. Kashiwagi, R. Sugise, T. Shimakawa, T. Matuura, M. Shirai, F. Kakiuchi, and S. Murai, Organometallics, 16 , 2233 (1997). 2) Ru3(CO)12-catalyzed Reaction of Pyridylbenzenes with Carbon Monoxide and Olefins. Carbonylation at a C-H Bond in the Benzene Ring N. Chatani, Y. Ie, F. Kakiuchi, and S. Murai, J. Org. Chem., 62, 2604 (1997). 1) Enantioselective Catalytic Ring Opening of Epoxides with Carboxylic Acids E. N. Jacobsen, F. Kakiuchi, R. G. Konsler, J. F. Larrow, and M. Tokunaga, Tetrahedron Lett., 38, 773 (1997). 【1996年】 4) Transition Metal-Catalyzed Intramolecular C-H/Olefin Coupling N. Fujii, F. Kakiuchi, N. Chatani, and S. Murai, Chem. Lett., 939 (1996). 3) Ru3(CO)12-Catalyzed Coupling of Heteroaromatic C-H/CO/Olefins. Regioselective Acylation of the Imidazole Ring. N. Chatani, T. Fukuyama, F. Kakiuchi, and S. Murai, J. Am. Chem. Soc., 118, 493 (1996). 2) Ruthenium-Catalyzed Addition of Aromatic Imines at the ortho C-H Bonds to Olefins F. Kakiuchi, M. Yamauchi, N. Chatani, and S. Murai, Chem. Lett., 111 (1996). 1) Ruthenium-Catalyzed Addition of Aromatic Esters at the ortho C-H Bonds to Olefins M. Sonoda, F. Kakiuchi, A. Kamatani, N. Chatani, and S. Murai, Chem. Lett., 109 (1996). 【1995年】 4) Directing Effect of Functional Groups in Ruthenium-Catalyzed Addition of Substituted Acetophenones to an Olefin M. Sonoda, F. Kakiuchi, N. Chatani, and S. Murai, J. Organomet. Chem., 504, 151 (1995). 3) Catalytic Addition of Aromatic C-H Bonds to Acetylenes F. Kakiuchi, Y. Yamamoto, N. Chatani, and S. Murai, Chem. Lett., 681 (1995). 2) Catalytic Addition of Olefinic C-H Bonds to Olefins F. Kakiuchi, Y. Tanaka, T. Sato, N. Chatani, and S. Mura, Chem. Lett., 679 (1995). 1) Catalytic Addition of Aromatic Carbon-hydrogen Bonds to Olefins with the Aid of Ruthenium Complexes F. Kakiuchi, S. Sekine, Y. Tanaka, A. Kamatani, M. Sonoda, N. Chatani, and S. Murai, Bull. Chem. Soc. Jpn., 68, 62 (1995). 【1994年】 1) Catalytic C-H/Olefin Coupling S. Murai, F. Kakiuchi, S. Sekine, Y. Tanaka, A. Kamatani, M. Sonoda, and N. Chatani, Pure Appl. Chem., 66, 1527 (1994). 【1993年】 4) Completely Selective Synthesis of (E)-β-(Triethylsilyl)styrenes by Fe3(CO)12-Catalyzed Reaction of Styrenes with Triethylsilane F. Kakiuchi, Y. Tanaka, N. Chatani, and S. Murai, J. Organomet. Chem., 456, 45 (1993). 3) Efficient Catalytic Addition of Aromatic Carbon-Hydrogen Bonds to Olefins S. Murai, F. Kakiuchi, S. Sekine, Y. Tanaka, A. Kamatani, M. Sonoda, and N. Chatani, Nature, 366, 529 (1993). 2) Dehydrogenative Silylation of 1,5-Dienes with Hydrosilanes Catalyzed by RhCl(PPh3)3 F. Kakiuchi, K. Nogami, N. Chatani, Y. Seki, and S. Murai, Organometallics 12, 4748 (1993). 1) Highly Selective Methyl Transfer from Methylsilanes to Phenylthallium(III) Crown Ether Complexes F. Kakiuchi, K. Furuta, S. Murai, and Y. Kawasaki, Organometallics, 12, 15 (1993). 【1992年】 2) Electrophilic Thallation of Thiophene Derivatives and Furan with Phenylthallium(III) 18-Crown-6 Diperchloroate F. Kakiuchi, S. Murai, and Y. Kawasaki, Organometallics, 11, 4352 (1992). 1) Electrophilic Thallation of Aniline Derivatives and Nitrogen Heterocycles with Phenylthallium(III) 18-Crown-6 Diperchlorate F. Kakiuchi, K. Ohe, N. Chatani, H. Kurosawa, S. Murai, and Y. Kawasaki, Organometallics, 11, 752 (1992). 【1991年】 1) Electrophilic Thallation of Phenol and Its Derivatives with Phenylthallium(III) Crown Ether Complexes F. Kakiuchi, Y. Kawasaki, N. Enomoto, H. Akita, K. Ohe, N. Chatani, H. Kurosawa, and S. Murai, Organometallics, 10, 2056 (1991). | |