原著論文に戻る

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＜総説＞

○ Catalytic C-H/Olefin Coupling
F. Kakiuchi and S. Murai
Acc. Chem. Res., 35, 826 (2002). <837>  doi

○ Catalytic Methods for C-H Bond Functionalization: Application in Organic Synthesis
F. Kakiuchi, N. Chatani
Adv. Synth. Catal., 345, 1077 (2003). <925>  doi

○ Transition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond Cleavage
F. Kakiuchi, T. Kochi
Synthesis, 3013 (2008). <631>  doi

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＜原著論文＞

52) Chain-Walking Strategy for Organic Synthesis: Catalytic Cycloisomerization of 1,n-Dienes
T. Kochi, T. Hamasaki, Y. Aoyama, J. Kawasaki, and F. Kakiuchi
J. Am. Chem. Soc., 134, 16544 (2012). <54>  doi

52) Catalytic Electrochemical C-H Iodination and One-Pot Arylation by On/Off Switching of Electric Current
H. Aiso, T. Kochi, H. Mutsutani, T. Tanabe, S. Nishiyama, and F. Kakiuchi
J. Org. Chem., 77, 7718 (2012). <54>  doi

36) Room-Temperature Regioselective C-H/Olefin Coupling of Aromatic Ketones Using an Activated Ruthenium Catalyst with a Carbonyl Ligand and Structural Elucidation of Key Intermediates
F. Kakiuchi, T. Kochi, E. Mizushima, and S. Murai
J. Am. Chem. Soc., 132, 17741 (2010). <71>  doi

10) Palladium-Catalyzed Aromatic C-H Halogenation with Hydrogen Halides by Means of Electrochemical Oxidation
F. Kakiuchi, T. Kochi, H. Mutsutani, N. Kobayashi, S. Urano, M. Sato, S. Nishiyama, and T. Tanabe
J. Am. Chem. Soc., 131, 11310 (2009). <166>  doi

34) Cleavage of C-N Bonds in Aniline Derivatives on a Ruthenium Center and Its Relevance to Catalytic C-C Bond Formation
T. Koreeda, T. Kochi, and F. Kakiuchi
J. Am. Chem. Soc., 131, 7238 (2009). <73>  doi

36) Ruthenium-Catalyzed Amino- and Alkoxycarbonylations with Carbamoyl Chlorides and Alkyl Chloroformates via Aromatic C-H Bond Cleavage
T. Kochi, S. Urano, H. Seki, E. Mizushima, M. Sato, and F. Kakiuchi
J. Am. Chem. Soc., 131, 2792 (2009). <71>  doi

19) The Ru(cod)(cot)-Catalyzed Alkenylation of Aromatic C-H Bonds with Alkenyl Acetates
Y. Matsuura, M. Tamura, T. Kochi, M. Sato, N. Chatani, and F. Kakiuchi
J. Am. Chem. Soc., 129, 9858 (2007). <108>  doi

17) Ruthenium-Catalyzed Carbon-Carbon Bond Formation via the Cleavage of an Unreactive Aryl Carbon-Nitrogen Bond in Aniline Derivatives with Organoboronates
S. Ueno, N. Chatani, and F. Kakiuchi
J. Am. Chem. Soc., 129, 6098 (2007). <118>  doi

15) Direct Observation of the Oxidative Addition of the Aryl Carbon-Oxygen Bond to a Ruthenium Complex and Consideration of the Relative Reactivity Between Aryl Carbon-Oxygen and Aryl Carbon-Hydrogen Bonds
S. Ueno, E. Mizushima, N. Chatani, and F. Kakiuchi
J. Am. Chem. Soc., 128, 16516 (2006). <120>  doi

7) A RuH₂(CO)(PPh₃)₃-Catalyzed Regioselective Arylation of Aromatic Ketones with Arylboronates via Carbon-Hydrogen Bond Cleavage
F. Kakiuchi, Y. Matsuura, Kan, S., and N. Chatani
J. Am. Chem. Soc., 127, 5936 (2005). <219>  doi

20) Ru₃(Co)₁₂-Catalyzed Silylation of Benzylic C-H Bonds in Arylpyridines and Arylpyrazoles with Hydrosilanes via C-H Bond Cleavage
F. Kakiuchi, K. Tsuchiya, M. Matsumoto, E. Mizushima, and N. Chatani
J. Am. Chem. Soc., 126, 12792 (2004). <107>  doi

9) Ruthenium-Catalyzed Functionalization of Aryl Carbon-Oxygen Bonds in Aromatic Ethers with Organoboron Compounds
F. Kakiuchi, M. Usui, S. Ueno, N. Chatani, and S. Murai
J. Am. Chem. Soc., 126, 2706 (2004). <167>  doi

26) The Ruthenium-Catalyzed Silylation of Aromatic C-H Bonds with Triethylsilane
F. Kakiuchi, M. Matsumoto, K. Tsuchiya, K. Igi, T. Hayamizu, N. Chatani, and S. Murai
J. Organomet. Chem., 686, 134 (2003). <94>  doi

4) A Ruthenium-Catalyzed Reaction of Aromatic Ketones with Arylboronates: A New Method for the Arylation of Aromatic Compounds via C-H Bond Cleavage
F. Kakiuchi, S. Kan, K. Igi, N. Chatani, and S. Murai,
J. Am. Chem. Soc., 125, 1698 (2003). <290>  doi

25) A New Chelation-Assistance Mode for A Ruthenium-Catalyzed Silylation at the C-H Bond in Aromatic Ring with Hydrosilanes
F. Kakiuchi, K. Igi, M. Matsumoto, T. Hayamizu, N. Chatani, and S. Murai
Chem. Lett., 396 (2002). <95>  doi

44) Ruthenium-Catalyzed Addition of Olefinic C-H Bonds in Conjugate Enones to Acetylenes to Give Conjugate Dienones
F. Kakiuchi, T. Uetsuhara, Y. Tanaka, N. Chatani, and S. Murai
J. Mol. Catal. A, 182, 511 (2002). <62>  doi

56) Mechanistic Study of the RuH₂(CO)(PPh₃)₃-Catalyzed Addition of C-H Bonds in Aromatic Esters to Olefins
F. Kakiuchi, H. Ohtaki, M. Sonoda, N. Chatani, and S. Murai
Chem. Lett., 918 (2001). <53>  doi

31) Ruthenium-Catalyzed Dehydrogenative Silylation of Aryloxazolines with Hydrosilanes via C-H Bond Cleavage
F. Kakiuchi, K. Igi, M. Matsumoto, N. Chatani, and S. Murai
Chem. Lett., 422 (2001). <76>  doi

30) The Ruthenium-Catalyzed Addition of β C-H Bonds in Aldehydes to Olefins
F. Kakiuchi, T. Sato, K. Igi, N. Chatani, and S. Murai
Chem. Lett., 386 (2001). <81>  doi

22) Atropselective Alkylation of Biaryl Compounds by Means of Transition Metal-Catalyzed C-H/Olefin Coupling
F. Kakiuchi, P. Le Gendre, A. Yamada, H. Ohtaki, and S. Murai
Tetrahedron: Asymmetry, 11, 2647 (2000). <100>  doi

52) A New Synthetic Route to Heteroarylsilanes via Ruthenium-Catalyzed C-H/SiR₃ Coupling
F. Kakiuchi, M. Matsumoto, M. Sonoda, T. Fukuyama, N. Chatani, S. Murai, N. Furukawa, and Y. Seki
Chem. Lett., 750 (2000). <54>  doi

33) The Ruthenium-Catalyzed Addition of C-H Bonds in Aromatic Nitriles to Olefins
F. Kakiuchi, M. Sonoda, T. Tsujimoto, N. Chatani, and S. Murai
Chem. Lett., 1083 (1999). <75>  doi

45) Ruthenium-Catalyzed Coupling of Aromatic Carbon-Hydrogen Bonds in Aromatic Imidates with Olefins
F. Kakiuchi, T. Sato, M. Yamauchi, N. Chatani, and S. Murai
Chem. Lett., 19 (1999). <61>  doi

35) New Protocol for the Site-Selective Alkylation and Vinylation of Aromatic Compounds. Catalyst-Specific Reactions
F. Kakiuchi, T. Sato, T. Tsujimoto, M. Yamauchi, N. Chatani, and S. Murai
Chem. Lett., 1053 (1998). <72>  doi

47) Ruthenium-Catalyzed Reactions of Acyclic α,β-Enones with Olefins and Their Reaction Mechanisms
T. Sato, F. Kakiuchi, N. Chatani, and S. Murai
Chem. Lett., 893 (1998). <58>  doi

41) Transition Metal-Catalyzed Intramolecular Cyclization of 1,5- and 1,6-Dienes via Direct Cleavage and Addition of the Carbon-Hydrogen Bond
N. Fujii, F. Kakiuchi, A. Yamada, N. Chatani, and S. Murai
Bull. Chem. Soc. Jpn., 71, 285 (1998). <69>  doi

18) Ruthenium-Catalyzed Addition of Carbon-Hydrogen Bonds in Aromatic Ketones to Olefins. The Effect of Various Substituents at the Aromatic Ring
M. Sonoda, F. Kakiuchi, N. Chatani, and S. Murai
Bull. Chem. Soc. Jpn., 70, 3117 (1997). <117>  doi

1) Asymmetric Catalysis with Water: Efficient Kinetic Resolution of Terminal Epoxides by Means of Catalytic Hydrolysis
M. Tokunaga, J. F. Larrow, F. Kakiuchi, and E. N. Jacobsen
Science, 277, 936 (1997). <1126>  doi

31) Asymmetric Intramolecular C-H/Olefin Coupling: Asymmetric Cyclization Reactions of 1,5-Dienes Catalyzed by Rhodium Complexes
N. Fujii, F. Kakiuchi, A. Yamada, N. Chatani, and S. Murai
Chem. Lett., 425 (1997). <76>  doi

6) Enantioselective Catalytic Ring Opening of Epoxides with Carboxylic Acids
E. N. Jacobsen, F. Kakiuchi, R. G. Konsler, J. F. Larrow, and M. Tokunaga
Tetrahedron Lett., 38, 773 (1997). <244>  doi

49) Transition Metal-Catalyzed Intramolecular C-H/Olefin Coupling
N. Fujii, F. Kakiuchi, N. Chatani, and S. Murai
Chem. Lett., 939 (1996). <56>  doi

14) Ruthenium-Catalyzed Addition of Aromatic Imines at the Ortho C-H Bonds to Olefins
F. Kakiuchi, M. Yamauchi, N. Chatani, and S. Murai
Chem. Lett., 111 (1996). <126>  doi

27) Ruthenium-Catalyzed Addition of Aromatic Esters at the Ortho C-H Bonds to Olefins
M. Sonoda, F. Kakiuchi, A. Kamatani, N. Chatani, and S. Murai
Chem. Lett., 109 (1996). <90>  doi

52) Directing Effect of Functional-Groups in Ruthenium-Catalyzed Addition of Substituted Acetophenones to an Olefin
M. Sonoda, F. Kakiuchi, N. Chatani, and S. Murai
J. Organomet. Chem., 504, 151 (1995). <54>  doi

8) Catalytic Addition of Aromatic C-H Bonds to Acetylenes
F. Kakiuchi, Y. Yamamoto, N. Chatani, and S. Murai
Chem. Lett., 681 (1995). <180>  doi

16) Catalytic Addition of Olefinic C-H Bonds to Olefins
F. Kakiuchi, Y. Tanaka, T. Sato, N. Chatani, and S. Murai
Chem. Lett., 679 (1995). <119>  doi

3) Catalytic Addition of Aromatic Carbon-Hydrogen Bonds to Olefins with the Aid of Ruthenium Complexes
F. Kakiuchi, S. Sekine, Y. Tanaka, A. Kamatani, M. Sonoda, N. Chatani, and S. Murai
Bull. Chem. Soc. Jpn., 68, 62 (1995). <306>  doi

38) Completely Selective Synthesis of (E)-β-(Triethylsilyl)styrenes by Fe₃(CO)₁₂-Catalyzed Reaction of Styrenes with Triethylsilane
F. Kakiuchi, Y. Tanaka, N. Chatani, and S. Murai
J. Organomet. Chem., 456, 45 (1993). <70>  doi

2) Efficient Catalytic Addition of Aromatic Carbon-Hydrogen Bonds to Olefins
S. Murai, F. Kakiuchi, S. Sekine, Y. Tanaka, A. Kamatani, M. Sonoda, and N. Chatani
Nature, 366, 529 (1993). <936>  doi


＊<>内は被引用回数（2019年3月9日 Web of Scienceにより調査）